1-{(Z)-1-(2,4-Dichlorophenyl)-1-[2-(4-methylphenoxy)ethoxy]prop-1-en-2-yl}-1H-imidazol-3-ium nitrate

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1-{(Z)-1-(2,4-Dichloro­phen­yl)-1-[2-(4-methyl­phen­oxy)eth­oxy]prop-1-en-2-yl}-1H-imidazol-3-ium nitrate

In the title salt, C21H21Cl2N2O2(+)·NO3(-), the imidazole ring makes dihedral angles of 43.39 (14) and 10.9 (2)° with the 4-methyl-phenyl and 2,4-dichloro-phenyl rings, respectively. The mol-ecule adopts a Z conformation about the C=C double bond, which links the imidazole ring to the 4-methyl-phen-oxy unit via an eth-oxy chain. In the crystal, cations and anions are linked into chains by N-H⋯O...

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Crystal structure of 2-ethyl-4-methyl-1-(2-oxido-3,4-dioxo­cyclo­but-1-en-1-yl)-1H-imidazol-3-ium

In the title inner salt molecule, C10H10N2O3, the four-membered cyclobutene ring is twisted by 7.1 (2)° with respect to the five-membered imidazole ring. The crystal packing exhibits an R 2 (2)(9) hydrogen-bonding ring motif through N-H⋯O and C-H⋯O inter-actions. The potential non-linear optical properties were studied by a computational ab initio calculations performed at the DFT/B3LYP/6-31++G...

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(Z)-3-(9-Anthryl)-1-(4-chloro­phen­yl)-2-(4-nitro-1H-imidazol-1-yl)prop-2-en-1-one

In the title compound, C(26)H(16)ClN(3)O(3), the dihedral angle between the anthracene mean plane and imidazole ring is 64.75 (2)°. In the crystal, π-π inter-actions between anthracene fragments lead to the formation of stacks of mol-ecules propagating in [100]. The short distance between the carbonyl groups of symmetry-related molecules [C⋯O = 2.985 (2) Å] indicates the existence of dipole-dip...

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(Z)-3-(9-Anthr­yl)-1-(4-bromo­phen­yl)-2-(4-nitro-1H-imidazol-1-yl)prop-2-en-1-one

In the title mol-ecule, C(26)H(16)BrN(3)O(3), the anthracene and benzene mean planes make dihedral angles of 63.79 (2) and 14.67 (2)°, respectively, with the plane of the imidazole ring. In the crystal structure, weak inter-molecular C-H⋯O hydrogen bonds link mol-ecules to form centrosymmetric dimers. Weak π-π stacking inter-actions, with centroid-centroid distances of 3.779 (2) and 3.826 (2) Å...

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1-[(Z)-8-(4-Chlorophenoxy)-3-(2,4-di­fluorophenyl)-4-oxaocta-2-en-2-yl]-1H-1,2,4-triazol-4-ium nitrate

In the title compound C(21)H(21)ClF(2)N(3)O(2) (+)·NO(3) (-), the triazole ring makes dihedral angles of 40.7 (3) and 30.2 (4)° with the 4-chloro-pheny and 2,4-difluoro-phenyl rings, respectively. The cation adopts a Z-configuration about the C=C double bond which links the triazole ring to the 4-chloro-phen-oxy unit via a but-yloxy chain. In the crystal, the cations and the anions are linked b...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812046181